Science deep dive · v1 2026-05-29

Air quality: VOCs & particulate matter

Indoor air is, on average, 2-5x more polluted than outdoor air (EPA). The dominant sources are not what most people guess: cleaning products, new construction materials, gas appliances, the act of cooking, and — increasingly — wildfire smoke intruding from outside.

The two-sentence summary

VOCs (volatile organic compounds) and PM2.5 (particulate matter ≤2.5 µm) account for most of the indoor air quality story for people with respiratory or cardiovascular sensitivity. Both are testable; both have specific, defensible action levels; both have specific, addressable source-control plays.

VOCs: what they are

Volatile organic compounds are carbon-based chemicals that evaporate at room temperature. The EPA defines them by their reactivity in atmospheric photochemistry; what matters in indoor air is which specific VOC, at what concentration, for how long.

The TO-15 method we sample against analyzes 62 common indoor VOCs. The ones that most often drive symptoms:

VOCCommon sourcesAction level
FormaldehydeComposite wood (MDF, particleboard), permanent-press fabrics, some insulations, smoking, off-gassing of new furnitureNIOSH REL 16 ppb 8-hr; ATSDR MRL 8 ppb chronic
BenzeneAttached-garage emissions, smoking, gasoline-powered toolsATSDR MRL 3 ppb chronic
Toluene + XylenePaint thinners, adhesives, vehicle exhaustNIOSH RELs
AcetaldehydeCombustion, smoking, some plasticsOEHHA REL 140 µg/m³
d-Limonene"Citrus"-scented cleanersNot regulated, but reacts with indoor ozone to form ultrafine particles + secondary aldehydes

"New house smell," "new car smell," the smell of a freshly painted room — all VOC-dominated. The smell fades because the dominant VOCs (formaldehyde, benzene, toluene) off-gas exponentially. Most of the off-gassing happens in the first 6-12 months; some materials keep emitting for years.

Where the VOCs come from (in order of frequency)

  1. Composite-wood furniture less than 2 years old (MDF and particleboard contain urea-formaldehyde adhesives).
  2. Recently installed cabinets, flooring, countertops.
  3. Recently painted rooms (latex paints emit less than oil- based, but still emit for 30+ days).
  4. Attached garage with combustion equipment (gas-powered mower, gasoline storage, car). Benzene + CO can intrude through the wall.
  5. Gas range / oven (formaldehyde + NO2 + CO).
  6. Aerosol sprays + scented cleaners.
  7. Smoking indoors (any), including vaping.
  8. Permanent-press / wrinkle-free clothing + bedding fresh from packaging.

How we sample VOCs

Active-pump sampling onto a Tenax sorbent tube for 60 minutes, analyzed by GC-MS for the TO-15 standard 62-compound list at an AIHA-LAP-accredited lab. The active-pump approach is more quantitative than passive badge sampling and catches transient sources (e.g. a cleaning event 4 hours before) that a 24-hour passive badge averages out.

Inspectors record what was happening in the home during the sample (cooking, recent cleaning, weather/HVAC state) so the interpretation accounts for the conditions.

Particulate matter: what it is

PM2.5 = solid + liquid particles ≤2.5 µm in aerodynamic diameter. Small enough to bypass nasal filtration and reach the alveoli; some fractions cross into the bloodstream. The cardiopulmonary literature on PM2.5 is one of the most robust in environmental health.

PM10 = particles ≤10 µm. Includes pollen, dust, larger combustion particles. Caught more efficiently by upper-airway defenses; the clinical concern is mostly upper-airway irritation + allergic sensitization.

EPA NAAQS (2024 revision):

PollutantThresholdAveraging period
PM2.59 µg/m³Annual
PM2.535 µg/m³24-hour
PM10150 µg/m³24-hour

The 2024 NAAQS revision tightened the annual PM2.5 standard from 12 to 9 µg/m³ — a meaningful shift that puts more indoor and outdoor environments out of compliance and re-frames what "moderate" AQI means clinically.

Where indoor PM2.5 comes from

  1. Cooking, especially gas + frying / searing. A single dinner can push PM2.5 to 200 µg/m³ in a closed kitchen.
  2. Gas appliances without exhaust to outside (stoves, dryers).
  3. Wildfire smoke intrusion through windows, HVAC fresh-air intakes, and building leaks.
  4. Wood-burning fireplace or stove, even when not in active use (intrusion via chimney downdraft).
  5. Vacuuming without a HEPA filter resuspends settled particulate.
  6. Candles, especially scented and paraffin.

How we sample PM

1-hour averaged real-time PM2.5 + PM10 readings using a light-scattering reference-grade instrument (DustTrak or equivalent), at both the indoor location of concern AND outdoors as a baseline. Same indoor/outdoor logic as our mold sampling — the question is amplification, not absolute level.

What we report

When to test

When NOT to test (yet)

Selected references

Last reviewed by Canary's clinical advisory board: 2026-05-29. Methodology → · Test catalog →